there is a lot more to it, and particularly for some people (with insulin resistance for instance) than just calories in and out. Do look at the support for low carb thread and also low GI foods, as it is increasingly evident that carbs are a really important factor in weight gain- as carbs turn straight into sugar if not used up.
This is how alcoholics drinks like beer or whisky are made, adding carbs like barley to turn into sugar and alcohol. Bonne chance.
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