In the days when hair was washed in soap, you always gave your hair a vinegar rinse after the wash to make sure the residues of the soap were not still in your hair to make it dull and sticky. Although, as a child my hair was washed with shampoo. My mother always finished my hairwash with a vinegar rinse, then ran a strand through her fingers to see if it squeaked, this being confirmation that all the soap/shampoo residues had been washed out.
I have always been very sparing in the use of household chemicals, no virtue, just parsimony and lack of cupboard space.
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