I think using no form of address is usually the safest option in a shop nowadays, Phoenix, though I don't dislike 'Madam' (or Sir) to such an extent that I would even think of complaining if someone addressed me that way. I just find it outdated.
The problem is that IMO it no longer seems appropriate for a young woman.
I doubt if any us would be likely to use it to address someone that we guessed was in their twenties, or even thirties, would we? Well I certainly wouldn't, anyway.
This means that the speaker has to make a decision based on how old someone looks to them, which can open up a whole can of worms. ?
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Once, I was returned to my ward bed after an op. for acute pancreatitis and gall bladder removal and when I surfaced, noticed the board said "Neil O'Reilly"; Not me !; until told it actually said "Nil Orally! i.e. total starvation, for one week; standard post op. treatment!
Mind you, my appetite wasn't what it used to be until fish-and-chips was back on the menu! 

